A seawater triggered dynamic coordinate bond and its application for underwater self-healing and reclaiming of lipophilic polymer† †Electronic supplementary information (ESI) available: Route of synthesis, details of characterization methods, and results of structure and property measurements. See DOI: 10.1039/c5sc03483c

A seawater triggered dynamic coordinate bond and its application for underwater self-healing and reclaiming of lipophilic polymer.

In this work, water triggered dynamic catechol-Fe3+ coordinate bonds are revealed and studied at atomic, molecular and macroscopic levels using Mössbauer spectroscopy, rheological analysis, etc. DOPA-iron complexation is found to be dynamic in the presence of water, and this dynamic manner is immobilized after removing water. Accordingly, a water saturated lipophilic polymer containing catechol...

Electronic Supplementary Information Seawater Triggered Dynamic Coordinate Bond and Its Application to Underwater Self-healing and Reclaiming of Lipophilic Polymer

Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion† †Electronic supplementary information (ESI) available: Preparation and physical characterization data of 1P and 2M, additional structural description, UV-Vis and CD spectra (Fig. S1–S7), crystallographic refinement details for 1P and 2M (Table S1), selected bond distances and angles for 1P and 2M (Tables S2–S5), ESI(+)-MS and ESI(+)-MSMS spectra (Fig. S8–S11 and Schemes S1 and S2) and PXRD (Fig. S12). CCDC 1046609 and 1046610. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01089f Click here for additional data file. Click here for additional data file.

Fluoride-promoted carbonylation polymerization: a facile step-growth technique to polycarbonates† †Electronic supplementary information (ESI) available: Experimental details for the synthesis and structural characterization of monomers and polymers, and kinetic study. See DOI: 10.1039/c6sc05582f Click here for additional data file.

Mechanism of the cooperative Si–H bond activation at Ru–S bonds† †Electronic supplementary information (ESI) available: Experimental procedures and computational details, characterization, crystallographic and quantum-chemical calculation data as well as NMR spectra. CCDC 1055362–1055364. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01035g

Institut für Chemie, Technische Universitä Berlin, Germany. E-mail: peter.hrobarik@ [email protected] Department of Chemistry, Graduate Scho Materials Science, Nagoya University, Furo-c † Electronic supplementary information ( and computational details, chara quantum-chemical calculation data 1055362–1055364. For ESI and crystallog format see DOI: 10.1039/c5sc01035g Cite this: Chem....